Level 1
ST 5 PE 6 EN 6 CH 1 IN 6 AG 10 LK 6
Lockpick, Science, and Small Guns
Level 2
Small Guns +12 (52), Lockpick +2 (34), Science +2 (34)
Swift Learner
Level 3
Lockpick +16 (50)
Lady Killer/Black Widow
Level 4
Science +16 (50)
Entomologist
Level 5
Small Guns +8 (60), Explosives +8 (25)
Iron Fist
Level 6
Small Guns +10 (70), Speech +6 (13)
Gunslinger
Level 7
Speech +12 (25), Medicine +4 (21)
Bloody Mess
Level 8
Medicine +16 (37)
Commando
Level 9
Repair +3 (20), Medicine +13 (50)
Toughness
Level 10
Repair +16 (36)
Finesse
Level 11
Sneak +2 (27), Repair +14 (50)
Mysterious Stranger
Level 12
Sneak +16 (43)
Sniper
Level 13
Sneak +7 (60), Speech +9 (34)
Silent Running
Bobblehead (Medicine)
Level 14
Speech +6 (40), Science +10 (60)
Cyborg
Level 15
Speech +10 (50), Barter +6 (13)
Robotics Expert
Level 16
Energy Weapons +1 (28), Barter +15 (28)
Action Boy/Girl
Level 17
Energy Weapons +16 (44)
Better Criticals
Level 18
Energy Weapons +16 (60)
Concentrated Fire
Level 19
Sneak +10 (70), Barter +6 (34)
Light Step
Level 20
Barter +16 (50)
Grim Reaper's Sprint
Level 21
Unarmed +11 (28), Medicine +5 (65)
Adamantium Skeleton
Level 22
Unarmed +16 (44)
Puppies!
Bobblehead (Unarmed)
Level 23
Unarmed +16 (70)
Paralyzing Palm
Level 24
Repair +10 (60), Melee Weapons +1 (16), Medicine +5 (70)
Iron Fist
Level 25
Melee Weapons +16 (32)
Iron Fist
Level 26
Melee Weapons +16 (48)
Nerves of Steel
Level 27
Melee Weapons +16 (64)
Life Giver
Grognak the Barbarian => Melee Weapons +1 (65)
Grognak the Barbarian => Melee Weapons +1 (66)
Bobblehead (Sneak)
Bobblehead (Melee Weapons)
Level 28
Explosives +12 (37), Melee Weapons +4 (80)
Ninja
Bobblehead (Explosives)
Level 29
Explosives +16 (63)
Pyromaniac
Level 30
Sneak +1 (83), Lockpick +6 (64), Unarmed +1 (79), Explosives +6 (77), Barter +1 (69), Big Guns +1 (26)
Almost Perfect
Bobblehead (Strength)
Bobblehead (Perception)
Bobblehead (Endurance)
Bobblehead (Charisma)
Bobblehead (Intelligence)
Bobblehead (Agility)
Bobblehead (Luck)
Bobblehead (Barter)
Bobblehead (Big Guns)
Bobblehead (Energy Weapons)
Bobblehead (Lockpick)
Bobblehead (Repair)
Bobblehead (Science)
Bobblehead (Small Guns)
Bobblehead (Speech)
Covert Ops
Please feel free to comment, or offer improvement suggestions (I haven't found any flaws yet!).
Oh, and enjoy playing! :)
Ross
Barter 81 + 23 (only 23 in game) = 104
Big Guns 38 + Infinite = 1xx
Energy Weapons 80 + 25 = 105
Explosives 79 + 25 = 104
Lockpick 79 + 25 = 104
Medicine 80 + 25 = 105
Melee Weapons 92 + 23 (2 already used) = 115
Repair 80 + 25 = 105
Science 83 + Infinite = 1xx
Small Guns 85 + 24 (1 requires Lawbringer) = 109
Sneak 83 + 25 = 108
Speech 80 + 25 = 105
Unarmed 81 + 25 = 106
Regarding wasting game time; you can gain all the levels / perks for this build by only collecting 2 of the Skill Books. This build is designed for somebody who wants to complete the game 100% and would be collecting all the books anyway.
I have also decided to include the Swift Learner perk because at level 2 or 3 you have to "waste" a perk as only the Black Widow / Lady Killer will benefit a maxed out character. All the other perks at this level either boost SPECIAL stats or Skill levels.