Level 1
ST 4 PE 5 EN 5 CH 4 IN 8 AG 6 LK 8
Speech, Sneak, and Small Guns
Bobblehead (Medicine)
Grognak the Barbarian => Melee Weapons +1 (15)
Level 2
Speech +9 (38), Explosives +9 (25)
Intense Training (IN)
Bobblehead (Intelligence)
Level 3
Lockpick +20 (36)
Lady Killer/Black Widow
Bobblehead (Strength)
Bobblehead (Perception)
Bobblehead (Charisma)
Bobblehead (Agility)
Bobblehead (Luck)
Bobblehead (Lockpick)
Bobblehead (Small Guns)
Bobblehead (Science)
Level 4
Small Guns +7 (53), Lockpick +1 (50), Speech +9 (50), Medicine +3 (40)
Educated
Bobblehead (Endurance)
Bobblehead (Barter)
Bobblehead (Big Guns)
Bobblehead (Explosives)
Bobblehead (Melee Weapons)
Bobblehead (Repair)
Bobblehead (Sneak)
Bobblehead (Speech)
Bobblehead (Unarmed)
Rad Regeneration
Level 5
Small Guns +7 (60), Lockpick +10 (60), Repair +3 (40), Science +3 (40)
Child at Heart
Ant Sight
Barkskin
Level 6
Small Guns +10 (70), Lockpick +13 (75)
Toughness
Wired Reflexes
Level 7
Sneak +3 (49), Science +10 (50), Medicine +10 (50)
Intense Training (CH)
Level 8
Speech +3 (65), Science +10 (60), Medicine +10 (60)
Strong Back
Covert Ops
Power Armor Training
Level 9
Small Guns +7 (80), Repair +4 (44), Science +12 (75)
Commando
Level 10
Sneak +1 (50), Lockpick +2 (80), Repair +15 (59), Science +5 (80)
Finesse
Bobblehead (Energy Weapons)
Level 11
Energy Weapons +2 (33), Repair +1 (60), Explosives +20 (60)
Animal Friend
Level 12
Energy Weapons +8 (41), Speech +15 (80)
Silent Running
Superior Defender
Ghoul Ecology
Level 13
Energy Weapons +13 (54), Repair +10 (70)
Robotics Expert
Level 14
Energy Weapons +13 (77), Medicine +10 (70)
Cyborg
Level 15
Sneak +10 (70), Energy Weapons +13 (90)
Sniper
Pitt Fighter
Booster Shot
Auto Expert
Level 16
Barter +23 (52)
Better Criticals
Hematophage
Level 17
Sneak +5 (75), Repair +10 (80), Barter +8 (60)
Action Boy/Girl
Level 18
Sneak +15 (90), Lockpick +5 (85), Science +3 (83)
Master Trader
Level 19
Explosives +10 (70), Science +2 (85), Medicine +10 (80), Big Guns +1 (30)
Life Giver
Level 20
Explosives +10 (80), Big Guns +13 (43)
Grim Reaper's Sprint
Level 21
Big Guns +23 (66)
Bloody Mess
Xenotech Expert
Level 22
Repair +8 (88), Science +5 (90), Medicine +10 (90)
Quantum Chemist
Punga Power!
Level 23
Lockpick +5 (90), Big Guns +18 (84)
Entomologist
Level 24
Small Guns +4 (84), Unarmed +5 (34), Speech +2 (82), Repair +2 (90), Explosives +4 (84), Melee Weapons +6 (34)
Demolition Expert
Level 25
Unarmed +11 (45), Melee Weapons +12 (46)
Demolition Expert
Level 26
Unarmed +12 (57), Melee Weapons +11 (57)
Nerves of Steel
Level 27
Unarmed +11 (68), Melee Weapons +12 (69)
Warmonger
Level 28
Unarmed +12 (80), Melee Weapons +11 (80)
Demolition Expert
Level 29
Unarmed +1 (81), Barter +21 (81), Melee Weapons +1 (81)
Explorer
Level 30
Small Guns +2 (90), Unarmed +3 (90), Speech +2 (90), Repair +4 (94), Explosives +6 (94), Barter +3 (90), Melee Weapons +1 (90), Big Guns +2 (92)
Almost Perfect
Every speech related perk is taken and you're speech is quite high early on making it always useful.
Every V.A.T.S perk except gunslinger and concentrated fire is taken. Sergeant York is a rifleman and is so proficient that concentrated fire is unnecessary. He has exactly what he needs. No more, no less.
Animal Friendship is something of a luxury, but Sergeant York gets along with everything except bugs. That's how he rolls.